The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Acylperoxy / CH3C(O)O2 / Moortgat(1989)_298K_195-280nm(resc,W-rev)

DATAFILE: CH3C(O)O2_Moortgat(1989)_298K_195-280nm(resc,W-rev).txt
NAME: acetylperoxy radical
FORMULA: CH3C(O)O2
AUTHOR(YEAR): Moortgat(1989)
T: 298K
λ: 195-280nm(resc,W-rev)
BIBLIOGRAPHY: G.K. Moortgat, B. Veyret, and R. Lesclaux, "Absorption spectrum and kinetics of reactions of the acetylperoxy radical", J. Phys. Chem. 93, 2362-2368 (1989); DOI: 10.1021/j100343a032
COMMENTS: W-rev = Wallington review
The absorption cross sections were rescaled by

T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase," Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008,

to the value σ(210nm) = 4.54×10-18 cm2 molecule-1 recommended for HO2

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